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Ensembles of climate model simulations are commonly used to separate externally forced climate change from internal climate variability. However, much of the information gained from running large ensembles is lost in traditional methods of data reduction such as linear trend analysis or large scale spatial averaging. This paper demonstrates a pattern recognition method (forced pattern filtering) that extracts patterns of externally forced climate change from large ensembles and identifies the forced climate response with up to 10 times fewer ensemble members than simple ensemble averaging. It is particularly effective at filtering out spatially coherent modes of internal variability (e.g., El Ni˜no, North Atlantic Oscillation), which would otherwise alias into estimates of regional responses to forcing. This method is used to identify forced climate responses within the 40-member Community Earth System Model (CESM) large ensemble, including an El-Ni˜no-like response to volcanic eruptions and forced trends in the North Atlantic Oscillation. The ensemble-based estimate of the forced response is used to test statistical methods for isolating the forced response from a single realization (i.e., individual ensemble members). Low-frequency pattern filtering is found to effectively identify the forced response within individual ensemble members and is applied to the HadCRUT4 reconstruction of observed temperatures, whereby it identifies slow components of observed temperature changes that are consistent with the expected effects of anthropogenic greenhouse gas and aerosol forcing. 

Dynamical cores used to study the circulation of the atmosphere employ various numerical methods ranging from finite‐volume, spectral element, global spectral, and hybrid methods. In this work, we explore the use of Flux‐Differencing Discontinuous Galerkin (FDDG) methods to simulate a fully compressible dry atmosphere at various resolutions. We show that the method offers a judicious compromise between high‐order accuracy and stability for large‐eddy simulations and simulations of the atmospheric general circulation. In particular, filters, divergence damping, diffusion, hyperdiffusion, or sponge‐layers are not required to ensure stability; only the numerical dissipation naturally afforded by FDDG is necessary. We apply the method to the simulation of dry convection in an atmospheric boundary layer and in a global atmospheric dynamical core in the standard benchmark of Held and Suarez (1994,https://doi.org/10.1175/1520-0477(1994)075〈1825:apftio〉2.0.co;2).

 

In this work, we examine the use of competitive 13 C kinetic isotope effects ( 13 C KIEs) on CO 2 reduction reactions that produce CO and formic acid as a means to formulate reaction mechanisms. The findings reported here mark a further advancement in the combined 13 C KIE measurements and theoretical calculations methodology for probing CO 2 conversion reactions.